1.
Immobilization of hydrochar in cellulose beads for eradicating paracetamol from synthetic and sewage water.
Senthil Kumar, P, Shanmugapriya, M, Prasannamedha, G, Rangasamy, G
Environmental pollution (Barking, Essex : 1987). 2024;:123035
Abstract
Sodium carboxymethyl cellulose polymer was used as a support matrix in immobilizing activated hydrochar derived from bamboo using hydrothermal carbonization. The structural and textural morphology of the beads were studied using FTIR, XRD, SEM/EDS, BET and TGA. Activated hydrochar showed a rough surface with irregular spherical shaped structure. Various oxygenated functional groups in composite beads and activated hydrochar were identified that assist in interaction with PARA pollutant. TGA analysis showed weight loss at three stages 200 °C, 365 °C and 710 °C that leads to complete disintegration of composite beads. BET analysis showed a variation in the surface area between activated hydrochar and beads which could be due to air drying process. Batch adsorption test was conducted for investigating the efficiency of beads in removing PARA from water. Pseudo-second order and Langmuir isotherm fitted the best highlighting chemical mode of adsorption with homogenous interaction on the adsorbent surface. 48.12 mg g-1 was the maximum adsorption capacity estimated from sorption between beads and PARA. For practical applications beads were effectively used in reducing COD levels of PARA spiked sewage water with the defined experimental parameters. Ethanol would be effectively used as regenerating solvent in recycling the beads for the betterment of cost reduction. The activated hydrochar immobilized cellulose beads would be successfully applied as adsorbent in removing target pollutants from water thereby reducing the hurdles faced with respect to fine particles in water treatment.
2.
Sustainable production of biosurfactants via valorisation of industrial wastes as alternate feedstocks.
Carolin C, F, Senthil Kumar, P, Mohanakrishna, G, Hemavathy, RV, Rangasamy, G, M Aminabhavi, T
Chemosphere. 2023;(Pt 1):137326
Abstract
Globally, the rapid increase in the human population has given rise to a variety of industries, which have produced a variety of wastes. Due to their detrimental effects on both human and environmental health, pollutants from industry have taken centre stage among the various types of waste produced. The amount of waste produced has therefore increased the demand for effective waste management. In order to create valuable chemicals for sustainable waste management, trash must be viewed as valuable addition. One of the most environmentally beneficial and sustainable choices is to use garbage to make biosurfactants. The utilization of waste in the production of biosurfactant provides lower processing costs, higher availability of feedstock and environmental friendly product along with its characteristics. The current review focuses on the use of industrial wastes in the creation of sustainable biosurfactants and discusses how biosurfactants are categorized. Waste generation in the fruit industry, agro-based industries, as well as sugar-industry and dairy-based industries is documented. Each waste and wastewater are listed along with its benefits and drawbacks. This review places a strong emphasis on waste management, which has important implications for the bioeconomy. It also offers the most recent scientific literature on industrial waste, including information on the role of renewable feedstock for the production of biosurfactants, as well as the difficulties and unmet research needs in this area.
3.
Adsorptive removal of phosphate from aqueous solutions using low-cost modified biochar-packed column: Effect of operational parameters and kinetic study.
Tran, TCP, Nguyen, TP, Nguyen, XC, Nguyen, XH, Nguyen, TAH, Nguyen, TTN, Vo, TYB, Nguyen, THG, Nguyen, TTH, Vo, TDH, et al
Chemosphere. 2022;(Pt 1):136628
Abstract
Adsorption in the continuous mode plays a significant role in wastewater treatment. In this study, Mimosa pigra-derived biochar modified with 2 M AlCl3 salt was used to pack a lab-scale column to eliminate PO43- from aqueous solutions. The influence of the operational factors, such as inlet PO43- concentration (25-100 mg/L), flow rate (6-18 mL/min), and biochar bed height (1.5-4.5 cm), on the breakthrough curve was evaluated. The kinetic models of Adam-Bohart and Yoon-Nelson were utilized to analyze the experimental results. The best conditions were determined to be the influent PO43- strength of 50 mg/L, injection speed of 6 mL/min, and column height of 4.5 cm. These results can be applied in the design of large-scale columns for the sequestration of PO43- from wastewater.
4.
A critical and recent developments on adsorption technique for removal of heavy metals from wastewater-A review.
Rajendran, S, Priya, AK, Senthil Kumar, P, Hoang, TKA, Sekar, K, Chong, KY, Khoo, KS, Ng, HS, Show, PL
Chemosphere. 2022;(Pt 2):135146
Abstract
This review provides a quantitative description of the nano-adsorbent processing and its viability against wastewater detoxification by extracting heavy metal ions. The impact of nano-adsorbent functionalities on specific essential attributes such as the surface area, segregation, and adsorption capacity were comprehensively evaluated. A detailed analysis has been presented on the characteristics of nanomaterials through their limited resistance to adsorb some heavy metal ions. Experimental variables such as the adsorbent dosage, pH, substrate concentration, response duration, temperature, and electrostatic force that influence the uptake of metal ions have been studied. Besides, separate models for the adsorption kinetics and isothermal adsorption have been investigated to understand the mechanism behind adsorption. Here, we reviewed the different adsorbent materials with nano-based techniques for the removal of heavy metals from wastewater and especially highlighted the nano adsorption technique. The influencing factors such as pH, temperature, dosage time, sorbent dosage, adsorption capacities, ion concentration, and mechanisms related to the removal of heavy metals by nano composites are highlighted. Lastly, the application potentials and challenges of nano adsorption for environmental remediation are discussed. This critical review would benefit engineers, chemists, and environmental scientists involved in the utilization of nanomaterials for wastewater treatment.